Boron—nitrogen compounds : LXX. Boron derivatives of 3,3′-diaminodipropylamine |
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Authors: | L Komorowski K Niedenzu |
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Institution: | Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506 U.S.A. |
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Abstract: | The reaction of borane(3) with 3,3′-diaminodipropylamine yields BH2B-bridge associated 3,3′-bis(dihydroborylamino)dipropylamino]dihydroborane, 1-aminopropyl-1,3,2-diazaboracyclohexane, or 1,8,10,9-triazaboradecalin (I), depending on the reaction conditions and the stoichiometry of the reactants. If tris(dimethylamino)borane is treated with 3,3′-diaminodipropylamine, only I or 1-bis-(dimethylamino)boryl-1,8,10,9-triazaboradecalin are obtained. |
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