On the dual canonical and Kazhdan-Lusztig bases and 3412-, 4231-avoiding permutations

Using Du’s characterization of the dual canonical basis of the coordinate ring O(GL(n,C)), we express all elements of this basis in terms of immanants. We then give a new factorization of permutations w avoiding the patterns 3412 and 4231, which in turn yields a factorization of the corresponding Kazhdan-Lusztig basis elements of the Hecke algebra H_n(q). Using the immanant and factorization results, we show that for every totally nonnegative immanant and its expansion with respect to the basis of Kazhdan-Lusztig immanants, the coefficient d_w must be nonnegative when w avoids the patterns 3412 and 4231.