| 二氨基二苯并-14-冠-4的合成与表征 |
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| 引用本文： | 郭凯,张淑媛,何可可,郑世军,张腾,阎涛,李自法.二氨基二苯并-14-冠-4的合成与表征[J].应用化学,2002,19(4):329-0. |
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| 作者姓名： | 郭凯 张淑媛 何可可 郑世军 张腾 阎涛 李自法 |
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| 作者单位： | 郑州大学 |
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| 基金项目： | 国家自然科学基金 (2 99740 2 6)，河南省自然科学基金资助项目 |
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| 摘 要： | 二硝基二苯并冠醚;二氨基二苯并冠醚;二氨基二苯并-14-冠-4的合成与表征
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| 关 键 词： | 二硝基二苯并冠醚 二氨基二苯并冠醚 二氨基二苯并-14-冠-4的合成与表征 |
| 文章编号： | 1000-0518(2002)04-0329-05 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2001年8月16日 |
Synthesis and Characterization of Diaminodibenzo-14-crown-4 |
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| GUO Kai a,ZHANG Shu Yuan b,HE Ke Ke a,ZHENG Shi Jun a,ZHANG Teng a,YAN Tao a,LI Zi Fa a.Synthesis and Characterization of Diaminodibenzo-14-crown-4[J].Chinese Journal of Applied Chemistry,2002,19(4):329-0. |
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| Authors: | GUO Kai a ZHANG Shu Yuan b HE Ke Ke a ZHENG Shi Jun a ZHANG Teng a YAN Tao a LI Zi Fa a |
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| Institution: | GUO Kai a,ZHANG Shu Yuan b,HE Ke Ke a,ZHENG Shi Jun a,ZHANG Teng a,YAN Tao a,LI Zi Fa a * |
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| Abstract: | Cis and trans dinitrodibenzo 14 crown 4 were synthesized via nitration of dibenzo 14 crown 4(DB14C4D) synthesized by a modified Pedersen method. Cis and trans diaminodibenzo 14 crown 4 ( cis DAmDB14C4 and trans DAmDB14C4) were obtained by reduction of NO 2 group using Pd/C catalyst. All the compounds were characterized by NMR, IR and elemental analysis. The stereo structures of the cis and trans diaminodibenzo 14 crown 4 in DMSO have been investigated by 1H NMR , 13 C NMR and computer simulation. |
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| Keywords: | dinitrodibenzo crown ether diaminodibenzo crown ether synthesis |
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