Calculation of the asymmetry parameters of the angular distribution and of the spin polarization of Auger electrons for open-shell atoms

By means of the multichannel Hartree-Fock-Dirac method, the parameters β and α₂ of the angular distribution of Auger electrons and the parameter β₂ of their spin polarization are calculated for sodium, krypton, xenon, barium, mercury, and excited argon. Relevant Coulomb matrix elements are determined by using orthogonal multielectron initial-and final-state wave functions for intermediate-type coupling in a relativistic approximation. Exchange interaction is taken into account in all calculations. A comparison of the results of calculations performed in the frozen-core approximation and those obtained with orthogonal initial-and final-state wave functions reveals that the relaxation of core orbital processes has only a slight effect on the anisotropy parameters of the angular distribution. The resulting values of the parameters β, α₂, and β₂ are compared with the results of different calculations.