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Synthesis of submicron-sized peanut-shaped poly(methyl methacrylate)/polystyrene particles by seeded soap-free emulsion polymerization
Authors:Shan Shia  Tao Wanga  Yan Tao Tanga  Li Min Zhoub  Shin Ichi Kurodab  a
Institution:a Key Laboratory of Applied Technology of Polymer Materials, College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China;b Department of Production Science and Technology, Faculty of Engineering, Gunma University, Ota 373-0057, Japan
Abstract:Submicron-sized peanut-shaped poly(methyl methacrylate)/polystyrene(PMMA/PS) particles were successfully synthesized by seeded soap-free emulsion polymerization of styrene on the spherical crosslinked PMMA seed particles.The obtained peanut-shaped particles showed a novel internal morphology:PS phase formed one domain which linked to the other domain having PMMA core encased by PS shell.
Keywords:Peanut-shaped  Seeded soap-free emulsion polymerization  Submicron-sized  Nonspherical particle
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