Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature |
| |
| Authors: | Kim Dong Eun Kim In Su Ratovelomanana-Vidal Virginie Genêt Jean-Pierre Jeong Nakcheol |
| |
| Affiliation: | Department of Chemistry, Korea University, Seoul, 136-701, Korea. |
| |
| Abstract: | An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20 degrees C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
