| 脱氟化氢聚偏氟乙烯膜的制备, 表征和导电性能的研究 |
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| 引用本文： | 洪洁,杨士勇,张旭庆,陆伟,张景云. 脱氟化氢聚偏氟乙烯膜的制备, 表征和导电性能的研究[J]. 化学学报, 1997, 55(8): 817-823 |
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| 作者姓名： | 洪洁 杨士勇 张旭庆 陆伟 张景云 |
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| 作者单位： | 中国科学院上海有机化学研究所 |
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| 基金项目： | 国家青年自然科学基金项目 |
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| 摘 要： | 聚偏氟乙烯(PVDF)膜与一些有机弱碱作用脱氟化氢(HF)生成表面为一氟乙炔(PFA)的膜。红外、紫外可见光谱分析表明脱HF的PVDF膜的共轭链结构比较规整。X光电子能谱、反应深度和接触度的分析表明, PVDF脱HF反应主要发生在膜表面。脱HF的PVDF膜(PFA)经各种掺杂剂掺杂后电导率上升5~6个数量级, 最高可达10^-^4s/cm, 且在掺杂过程中出现出的性质不同于聚乙炔。
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| 关 键 词： | 紫外分光光度法 红外分光光度法 光谱分析 Ｘ射线光电子谱法 聚偏氟乙烯 导电性 氟化氢 |
Study on preparation, characterization and electrical property of dehydrofluorinated poly (vinylidene fluoride) film |
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| HONG JIE,YANG SHIYONG,ZHANG XUQING,LU WEI,ZHANG JINGYUN. Study on preparation, characterization and electrical property of dehydrofluorinated poly (vinylidene fluoride) film[J]. Acta Chimica Sinica, 1997, 55(8): 817-823 |
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| Authors: | HONG JIE YANG SHIYONG ZHANG XUQING LU WEI ZHANG JINGYUN |
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| Abstract: | The reactions of poly (vinylidene fluoride) (PVDF) film with some organic weak bases produce dehydrofluorinated product-polyfluorinated acetylene (PFA) on the two surfaces of the film. An orderly conjugated structure of the dehydrofluorinated film is suggested by IR and UV-VIS spectra. Inestigations by XPS, reaction depth and contact-angle hysteresis indicated that the two surfaces of PVDF film are the main reaction site. The conductivity of the dehydrofluorinated PVDF films are raised 5~6 magnitude of orders after doping by various dopants. The maximum value reaches 10^-^4s/cm. The doping behavior of the dehydrofluorinated PVDF film is different from that of polyacetylene. |
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| Keywords: | ULTRAVIOLET SPECTROPHOTOMETRY INFRARED SPECTROPHOTOMETRY SPECTROGRAPHIC ANALYSIS X-RAY PHOTOELECTRON SPECTROMETRY POLYVINYLIDENE FLUORIDE ELECTRICAL CONDUCTIVITY HYDROGEN FLUORIDE |
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