An efficient catalytic oxidation of p-Alkoxypenols to p-quinones using tetrabutylammonium bromide and oxone |
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| Authors: | Yakura Takayuki Ozono Ayaka Morimoto Kohei |
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| Affiliation: | Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama, Sugitani, Toyama, Japan. yakura@pha.u-toyama.ac.jp |
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| Abstract: | A catalytic oxidation of p-alkoxyphenols was developed using tetrabutylammonium bromide (TBAB) and Oxone(?). The reaction of p-alkoxyphenol (1) with a catalytic amount of TBAB in the presence of Oxone(?) as a co-oxidant in acetonitrile-water (2 : 1) gave the corresponding p-quinone (2) in excellent yield without special treatment. |
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