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Ultrahigh Electron Emissive Carbon Nanotubes with Nano-sized RuO2 Particles Deposition
Authors:Ruth Knibbe  Kazuhiro Nogita  John Drennan  Tsuneyuki Noguchi  Katsuyoshi Tatenuma  Pou Liu  Fumihito Arai  Eiji Yashima  Michiru Nishiwaki  Shigeki Kato
Institution:(1) Department of Chemical Engineering, The University of Queensland, 50 Coopers Rd., St. Lucia, Brisbane, QLD, 4072, Australia;(2) The Graduate University for Advanced Studies, Ohho 1-1, Tsukuba Ibaraki, 305-0801, Japan;(3) KAKEN Inc., 1044 Hori, Mito Ibaraki, 310-0903, Japan;(4) Nagoya University, Nagoya 464-8603, Japan;(5) High Energy Accelerator Research Organization (KEK), Ohho 1-1, Tsukuba Ibaraki, 305-0801, Japan
Abstract:Multi-wall carbon nanotubes (MWNTs) have a great commercial potential as electron field emitters, but suffer from fundamental problems such as stability and brightness. By depositing the MWNTs with nano-sized ruthenium dioxide (RuO2) particles, a new high performance emitter has been developed. When compared to MWNTs, the MWNTs impregnated with 1–2 nm sized RuO2 have superior and more efficient electrical characteristics. MWNTs supported by a silicon substrate showed a reduction in the onset voltage from 5.4 to 4 V/μm after RuO2 impregnation. The long-term stability of the impregnated MWNTs is also demonstrated with only a 20% increase in applied voltage required after 700 h operation at 40 mA/cm2.
Keywords:field emission  MWNT  RuO2            electrical characteristics
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