The syntheses and crystal structures of two chromium(III) and molybdenum(III) coordination compounds with 4-ethylpyridine |
| |
| Authors: | Barbara Modec Jruij V. Brenčnič Gerald Giester |
| |
| Affiliation: | (1) Faculty of Chemistry and Chemical Technology, University of Ljubljana, A!["scaron"]("/content/j3m0444627218w44/xlarge353.gif") ker!["ccaron"]("/content/j3m0444627218w44/xlarge269.gif") eva 5, 1000 Ljubljana, Slovenia;(2) Faculty of Chemistry and Chemical Technology, University of Ljubljana, Akereva 5, 1000 Ljubljana, Slovenia;(3) Institut für Mineralogie und Kristallographie, Universität Wien, Geozentrum, Althanstrasse 14, A-1090 Wien, Austria |
| |
| Abstract: | The structures of trichlorotris(4-ethylpyridine)chromium(III), [CrCl3(C7H9N)3] (I), and trichlorotris(4-ethylpyridine)molybdenum(III), [MoCl3(C7H9N)3] (II), consist of neutral molecules where three 4-ethylpyridine and three chloro ligands coordinate to the metal with a meridional configuration. Compound I crystallizes in a trigonal space group P31 with a = 11.515(2) Å and c = 15.378(3) Å. Compound II crystallizes in a monoclinic space group C2/c with a = 24.200(3) Å, b = 18.089(3) Å, c = 22.6004(7) Å and  = 106.7137(6)°. |
| |
| Keywords: | Chromium(III) molybdenum(III) 4-ethylpyridine complexes |
| 本文献已被 SpringerLink 等数据库收录！ |
|
