Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides |
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| Authors: | Shintani Ryo Kimura Takahiro Hayashi Tamio |
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| Institution: | Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Japan. |
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| Abstract: | Rhodium/chiral diene (S,S)- complex has been found to effectively catalyze the 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides, furnishing useful beta-chiral Weinreb amides in high enantioselectivity. |
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