Selective dimerization,oligomerization, homopolymerization and copolymerization of olefins with complex organometallic catalysts |
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Authors: | G. P. Belov |
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Affiliation: | (1) Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Russia |
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Abstract: | Review embarrasses the problems of low molecular weight olefins (ethylene and propylene) selective oligomerization to butene-1, hexene-1, octene-1, 4-methylpentene-1; selective polymerization of olefins to obtain polymers with a given molecular mass, molecular mass distribution, branching (for the polyethylene), chain structure [atactic, iso-, syndio-, gemiisotactic, stereoblock type and containing terminal vinyl and vinylidene bonds (for polypropylene)]; “live” homo-and copolymerization of olefins, and alternating copolymerization of olefins in the presence of complex organometallic catalysts. |
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