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Adsorption of fluids on solid surfaces: A route toward very dense layers
Authors:S.A. Sartarelli  L. Szybisz
Affiliation:1. Instituto de Desarrollo Humano, Universidad Nacional de General Sarmiento, San Miguel, Argentina;2. Laboratorio TANDAR, Departamento de Física, Comisión Nacional de Energía Atómica, RA-1429 Buenos Aires, Argentina;3. Departamento de Fíica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina;4. Consejo Nacional de Investigaciones Científicas y Técnicas, RA-1033 Buenos Aires, Argentina
Abstract:Adsorption of Xe on single planar walls is investigated in the frame of a density functional theory. The strength of the adsorbate-substrate attraction is changed by considering surfaces of Cs, Na, Li, and Mg. The behavior is analyzed by varying the temperature T (between the triple point Tt and the critical Tc) and the coverage Γ?Γ?. The obtained adsorption isotherms exhibit a variety of wetting situations. Density profiles are reported. It is shown that for strongly attractive surfaces the adsorbed liquid becomes very dense reaching densities characteristic of solids.
Keywords:Wetting   Structure of simple liquids   Liquid&ndash  vapor transitions
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