Strong-coupling electrostatics for two dissimilar charged walls |
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Authors: | L. &Scaron amaj,E. Trizac |
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Affiliation: | 1. Institute of Physics, Slovak Academy of Sciences, Dúbravská cesta 9, 84511 Bratislava, Slovakia;2. Laboratoire de Physique Théorique et Modèles Statistiques, UMR CNRS 8626, Université Paris-Sud, 91405 Orsay, France |
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Abstract: | We study the effective interaction between two parallel charged plates, modelling macromolecules, or colloids, in the strongly coupled Coulomb regime. Neutralizing mobile ions are point-like and confined in the inter-plate slab. A cumulant technique provides exact expansions, beyond the leading strong-coupling order, that are in remarkable agreement with simulation data for both the ionic profile and the inter-plate pressure. The present approach amounts to a summation over relevant excitations around the Wigner Crystal ground state formed at infinite coupling; It thereby differs from previous virial-like strong-coupling theories and generalizes a recent work by the authors to asymmetric plates. |
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Keywords: | Coulomb systems Strong coupling Wigner Crystal |
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