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| 硫代钼酸盐和硫代钨酸盐的合成性质和取代反应的研究 | |
| 引用本文： | 金国新,忻新泉,陈汉文,郑兴福,戴安邦. 硫代钼酸盐和硫代钨酸盐的合成性质和取代反应的研究[J]. 无机化学学报, 1987, 3(4): 106-112 |
| 作者姓名： | 金国新 忻新泉 陈汉文 郑兴福 戴安邦 |
| 作者单位： | 南京大学配位化学研究所(金国新，忻新泉，陈汉文，郑兴福)，南京大学配位化学研究所(戴安邦) |
| 摘 要： | 本文提出了在水或水/醇溶液中[NH_4]_2[MO_nS_(4-n)](M=Mo、W,n=0-2)进行取代反应的方法。用该方法合成出[X]_2[MO_nS_(4-n)](X=(n-Bu)_4N、Ph_4P、py—C_(16)H_(33)共18个化合物,其中11个为新化合物,并采用元素分析、红外光谱、电子光谱和X-粉末衍射等方法对这些化合物进行了表征。 |
| 关 键 词： | 硫代铝酸盐 硫代钨酸盐 取代反应 |
| 收稿时间： | 1987-04-02 |
STUDY ON SYNTHESIS, PROPERTIES AND SUBSTITUTION REACTIONS OF THIOMOLYBDATE AND THIQTUNG STATE |
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| Jin Guoxin,Xin Xinquan,Chen Hanwen,Zheng Xinfu and Dai Anbang. STUDY ON SYNTHESIS, PROPERTIES AND SUBSTITUTION REACTIONS OF THIOMOLYBDATE AND THIQTUNG STATE[J]. Chinese Journal of Inorganic Chemistry, 1987, 3(4): 106-112 | |
| Authors: | Jin Guoxin Xin Xinquan Chen Hanwen Zheng Xinfu Dai Anbang |
| Affiliation: | Coordination Chemistry Institute, Nanjing University,Coordination Chemistry Institute, Nanjing University,Coordination Chemistry Institute, Nanjing University,Coordination Chemistry Institute, Nanjing University and Coordination Chemistry Institute, Nanjing University |
| Abstract: | This paper reports the preparation of [NX4]2[MOuS4-n] (M = Mo or W, n = 0-2) in solution or in aqueous/alcohol solution by substitution reaction method. The reaction condition is mild and yields are generally good. Eighteen compounds with the formula, [X]2 [MOnS4-n] [X = [n-Bu)4N, Ph4P, py-C18H33], have been prepared, of which 11 are new, characterized by chemical analysis, electronic spectra, IR spectra and X-ray powder diffraction. |
| Keywords: | thiomolybdate thiotungstate substitution reaction. |
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