Thermal decomposition of metal complexes: II. Mixed complexes of iron(II) iodide with 1,10-phenanthroline,and 4,7-disubstituted-1,10-phenanthrolines |
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| Authors: | R.P. Bonomo S. Gurrieri S. Musumeci E. Rizzarelli G. Siracusa |
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| Affiliation: | Istituto di Chimica Generale dell''Università di Catania, Viale A. Doria, 8-95125 Catania Italy |
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| Abstract: | The thermal behavior of the Fe(II) iodide mixed complexes with 1,10-phenanthroline and 4,7-disubstituted phenanthrolines in nitrogen atmosphere is investigated.In order to determine to what extent small changes in ligand field symmetries influence the “activation energy” E★a, this energy is determined. The results are discussed in relation to the changes of the σ and π bonds. |
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