Electrical and magnetic properties of single crystal [NEt4]2[CuII(mnt)2] |
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Authors: | KW Plumlee BM Hoffman MT Ratajack CR Kannewurf |
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Institution: | Department of Chemistry, Northwestern University, Evanston, Illinois 60201, U.S.A.;Department of Electrical Engineering, Northwestern University, Evanston, Illinois 60201, U.S.A. |
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Abstract: | We report electrical and magnetic studies of NEt4]2CuII(mnt)2]. This crystal is composed of chains of theplanar CuII(mnt)2]?2 anions (space group and z = 1) which exhibit only weak magnetic interactions. The material behaves as a semiconductor; from 300–400°K the conductivity increases by six orders of magnitude and the resistivity values above 300°K are comparable to those of some of the better known wide band-gap inorganic semiconductors. In contrast with the behavior of other linear chain systems, at room temperature the conductivity along the chain (σ∥) is less than that perpendicular to the chain (σ⊥). As the temperature is increase, the anisotropy ratio, σ∥/σ⊥, becomes greater than unity and increases to 1.6 × 102 at 400°K. |
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