A water-stable lanthanide-coordination polymer with free Lewis site for fluorescent sensing of Fe3+ |
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Authors: | Wenhe Wang Qiang Gao Xiaoyu Li Jianhong Wang Chaopeng Wang Yinghui Zhang Xianhe Bu |
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Institution: | a Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China;
b School of Materials Science and Engineering, TKL of Metal-and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China |
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Abstract: | A new fluorescent coordination polymer (NKU-115) was constructed under solvothermal condition based on Tb3+ ion and H2L (5-(4H-1,2,4-triazol-4-yl) benzene-1,3-dicarboxylic acid) ligand, featuring high solvent and water stability. Luminescent investigations revealed that NKU-115 shows fluorescence quenching response toward Fe3+ in aqueous solution and the mechanism of quenching was analyzed. |
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Keywords: | Lanthanide-based coordination polymers Fluorescent sensing Aqueous solution Lewis site Iron ion |
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