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A water-stable lanthanide-coordination polymer with free Lewis site for fluorescent sensing of Fe3+
Authors:Wenhe Wang  Qiang Gao  Xiaoyu Li  Jianhong Wang  Chaopeng Wang  Yinghui Zhang  Xianhe Bu
Institution:a Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China; b School of Materials Science and Engineering, TKL of Metal-and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China
Abstract:A new fluorescent coordination polymer (NKU-115) was constructed under solvothermal condition based on Tb3+ ion and H2L (5-(4H-1,2,4-triazol-4-yl) benzene-1,3-dicarboxylic acid) ligand, featuring high solvent and water stability. Luminescent investigations revealed that NKU-115 shows fluorescence quenching response toward Fe3+ in aqueous solution and the mechanism of quenching was analyzed.
Keywords:Lanthanide-based coordination polymers  Fluorescent sensing  Aqueous solution  Lewis site  Iron ion
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