Thermodynamic properties of methylvinylsulphide |
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| Authors: | LS Gormely J Lielmezs |
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| Institution: | Chemical Engineering Department, The University of British Columbia, Vancouver 8, B.C. Canada |
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| Abstract: | Enthalpies of the overall decomposition reactions MX2L2(c) → MX2(c) + 2L(g) and of the intermediate stepwise loss of ligand, L, where X is Cl or Br; L is 3-chloropyridine, 3-bromopyridine, 2-chloropyridine, 2-bromopyridine, or 2-methoxypyridine; and M is Mn, Ni, Cu, or Cd have been measured by use of a differential scanning calorimeter. Enthalpies of sublimation of NiCl2(3-chloropyridine)2, NiCl2(3-bromopyridine)2 and CuCl2(3-bromopyridine)2 have been determined. Values of the metal—nitrogen bond dissociation energies in these compounds have been calculated. A value for the specific heat of CuCl2(2-chloropyridine)2 is reported. |
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