| 分子内孤对(n)轨道间相互作用的又一例证——某些杂氮环已烷系列化合物的气相HeIα紫外光电子能谱(UPS)研究 |
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| 引用本文： | 王殿勋,王东,赵恒奇,唐青,徐广智.分子内孤对(n)轨道间相互作用的又一例证——某些杂氮环已烷系列化合物的气相HeIα紫外光电子能谱(UPS)研究[J].物理化学学报,1992,8(6):809-813. |
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| 作者姓名： | 王殿勋 王东 赵恒奇 唐青 徐广智 |
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| 作者单位： | Institute of Chemistry, Academia Sinica, Beijing 100080 |
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| 摘 要： |
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| 关 键 词： | UPS 杂氮环乙烷 轨道相互作用 |
| 收稿时间： | 1991-07-08 |
| 修稿时间： | 1991-12-09 |
An Example of Lone Pair Orbital and Their Interaction——Gas Phase Ultravlolet Photoelctron Spectroscople Study of some Nitrogen Heterocyclle Compounds |
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| Wang Dian-Xun,Wang Dong,Zhao Heng-Qi,Tang Qing,Xu Guang-Zhi.An Example of Lone Pair Orbital and Their Interaction——Gas Phase Ultravlolet Photoelctron Spectroscople Study of some Nitrogen Heterocyclle Compounds[J].Acta Physico-Chimica Sinica,1992,8(6):809-813. |
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| Authors: | Wang Dian-Xun Wang Dong Zhao Heng-Qi Tang Qing Xu Guang-Zhi |
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| Institution: | Institute of Chemistry, Academia Sinica, Beijing 100080 |
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| Abstract: | Ione pair orbital and their interaction in some nitrogen heterocyclic compound series have been interpreted in terms of through-space and through-bond mechanisms through the study of their gas phase ultraviolet photoelectron spectrocopy. The HAM/3 molecular orbital calculations on each molecule of the studied series were also carried out. The order of experimental vertical ionization potentials of the molecules can be not only predicated, but the spacing of through-space and through-bond interactions splitting of the studied compounds are consistent with the results of HAM/3 calculations. |
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| Keywords: | Ultraviolet photoelectron Spectroscopy Heterocycles Orbital interaction |
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