The synthesis of 11β-alkyl-19-norsteroids: a novel class of potent steroid hormones—I : The synthesis of 11β-methyl and 11β-ethylestradiol |
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Authors: | JS Baran DD Langford I Laos CD Liang |
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Institution: | Department of Chemistry, Searle Laboratories, Skokie, IL 60076, U.S.A. |
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Abstract: | The syntheses of 11β-methyl and 11β-ethylestradiol, via Grignard adducts to 11-oxoestra-1,3,5(10)-trienes, attempted modification of the Torgov total synthesis of steroids, and 11β-methylticogenin, are described. |
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