The relationship between properties of fluorinated graphite intercalates and matrix composition |
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Authors: | D V Pinakov V A Logvinenko G N Chekhova Yu V Shubin |
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Institution: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, Novosibirsk-90, 630090, Russia |
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Abstract: | Inclusion compounds (intercalates) of fluorinated graphite matrix with acetone (C2F
x
Br
z
·y(CH3)2CO, x = 0.49, 0.69, 0.87, 0.92, z ≈ 0.01) were prepared by guest substitution from acetonitrile to acetone. The kinetics of the thermal decomposition (the
first stage of filling → the second stage of filling) was studied under isothermal conditions at 292–313 K. The relationship
of the host matrices structure with inclusion compounds thermal properties and kinetic parameters is discussed. |
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Keywords: | |
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