Improved accuracy in the determination of polycyclic aromatic hydrocarbons in air using 24 h sampling on a mixed bed followed by thermal desorption capillary gas chromatography-mass spectrometry

A new sampling method for the determination of polycyclic aromatic hydrocarbons (PAHs) in ambient air is described. The method is based on active sampling on sorption tubes consisting of polydimethylsiloxane (PDMS) foam, PDMS particles and a TENAX TA bed. After sampling, the solutes are quantitatively recovered by thermal desorption and analysed by capillary GC-MS. The new sampling method has been compared to the classical method using high-volume sampling on a glass fiber filter followed by polyurethane foam for 24h sampling of ambient air. Volumes enriched were 144 l on the mixed bed and 1296 m3 with the classical method. The concentrations measured using the new method were significantly higher that the values obtained using the classical method, i.e. a factor 1.2-3 for the high molecular weight PAHs and up to 35 times for naphthalene and 23 times for acenaphthene. The total toxicity equivalence value (TEQ) for PAHs was ca. two times higher compared to the conventional method, illustrating that the concentrations of PAHs in ambient air have been underestimated until now. Some figures of merit (mean value for 17 PAHs) of the method are repeatability 7.4%, detection limit 13 pg/m3, accuracy 105.6% and linearity 0.996. The method also opens interesting perspectives for the determination of other semi-volatile persistent organic pollutants (POPs) in air as illustrated with the analysis of polychlorinated biphenyls (PCBs) at a workplace during removal of transformer oil.