Metal complexes as indicators of solvent structures. Part IV. The effect of solvation on the interaction between tris-1,2-diaminoethanecobalt(III) and anions in aqueous solution |
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| Authors: | Robert D. Gillard |
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| Affiliation: | (1) School of Chemistry and Applied Chemistry, University of Wales College of Cardiff, P.O. Box 912, CF1 2TB Cardiff, Wales, U.K. |
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| Abstract: | Summary Changes in the circular dichroism of (+)tris-1,2-diaminoethanecobalt(III) in the presence of sulphate ion can be attributed to changes in the cybotactic solvation of the complex ion as well as to the formation of discrete ion-pairs.Parts 1, 2 and 3: R. D. Gillard and H. M. Sutton,J. Chem. Soc., A, (1970) 1309, 2172 and 2175 respectively. |
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