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Preparation of azafullerene derivatives from fullerene-mixed peroxides and single crystal X-ray structures of azafulleroid and azafullerene |
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| Authors: | Zhang Gaihong Huang Shaohua Xiao Zuo Chen Quan Gan Liangbing Wang Zheming |
| Affiliation: | Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. |
| Abstract: | Azafullerene was prepared by addition of hydroxylamine to a cage-opened fullerendione derivative and subsequent PCl5 induced rearrangement processes. X-ray structures were obtained for the azafullerene and its azafulleroid precursor. |
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