Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes |
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| Authors: | Barman Samir Furukawa Hiroyasu Blacque Olivier Venkatesan Koushik Yaghi Omar M Jin Guo-Xin Berke Heinz |
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| Institution: | Department of Inorganic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland. |
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| Abstract: | Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648. |
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