pH-Driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes |
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| Authors: | Álvarez Celedonio M Carrillo Romen García-Rodríguez Raúl Miguel Daniel |
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| Affiliation: | Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, C/Prado de la Magdalena s/n, E-47071, Valladolid, Spain. |
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| Abstract: | Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre. |
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