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1-Hydro-3-vinylhexamethylcyclotetrasiloxane and its polymerization
Authors:K A Andrianov  V I Sidorov  M G Zaitseva  L M Khananashvili
Institution:(1) Lomonosov Moscow Institute of Precision Chemical Engineering, USSR
Abstract:1,3-Dimethyl-3-vinyl-1,3-dichlorosiloxane is prepared by partial cohydrolysis of methylvinyldichlorosilane and methyldichlorosilane, and its cohydrolysis with sym-tetra-methyldichlorodisiloxane gives 1-hydro-3-vinylhexamethyl-cyclotetrasiloxane. A study is made of the kinetics of the polymerization of the latter in CCL4 in the presence of H2PtCl6 · 6H2O
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