Polycatenate Structure and Thermal Analysis of a New 2D + 2D Cobalt(II) Coordination Polymer Based on 5-Methoxylisophthalic Acid and 3,5-Bis(imidazole-1-yl)pyridine Co-Ligands |
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Authors: | Y F Wang J J Wei X H Zhai |
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Institution: | 1.College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials,Luoyang Normal University,Luoyang,P.R. China |
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Abstract: | A new Co(II) compound, namely Co(CH3O-H2Ip)(Bip)] n (I) (CH3O-H2Ip = 5-methoxylisophthalic acid and Bip = 3,5-bis(imidazole-1-yl)pyridine), has been synthesized through combination of CH3O-H2Ip, Bip and Co(II) acetate under hydrothermal condition and structurally characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction (CIF file CCDC no. 977220). It crystallizes in triclinic, space group P1? with a = 9.764(6), b = 10.106(6), c = 11.673(7) Å, α = 104.12970°, β = 100.601(7)°, γ = 105.324(7)°, V = 1038.6(11) Å3, C20H16CoN5O5, Mr = 465.31, Z = 2, ρcalcd = 1.488 g/cm3, μ(MoKα) = 0.869 mm?1, F(000) = 476, the final R = 0.0652 and wR = 0.1530. The X-ray analysis demonstrates that compound I exhibits a 2D + 2D polyrotaxane (4, 4) net network. Moreover, the thermal analysis of compound I has also been investigated. |
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