Synthesis and Optoelectronic Properties of a Pt(II) Complex with 2-Pyridin-2-Yl-1,3-Thiazole-4-Carboxylic Acid |
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| Authors: | X P Zhang D S Zhang W Sun Z F Shi |
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| Institution: | 1.College of Chemistry and Chemical Engineering,Hainan Normal University,Haikou,P.R. China;2.Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province,Haikou,P.R. China |
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| Abstract: | A carboxyl functionalized Pt(II) complex PtC9H6N2O2SCl2 (I) has been synthesized by the coordination reaction of K2PtCl4 with 2-pyridin-2-yl-1,3-thiazole-4-carboxylic acid. The absorption property and photosensitizing performance of I has been studied. Through assembling the dye-sensitized solar cells (DSSCs) based on complex I, a weak solar-energy-to-electricity conversion is presented. Additionally, when complex I was solved in DMF solution, a novel complex PtC9H7N2O3SCl (II) could be obtained. The structure of II has been confirmed by the single-crystal X-ray diffraction (CIF file CCDC no. 1538911). |
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