Polymer-solvent effects in cellulose urethane and methyl cellulose urethane solutions |
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Authors: | E Klohr P Zugenmaier |
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Institution: | (1) Institut für Physikalische Chemie, Technische Universität Clausthal, Arnold-Sommerfeld-Str. 4, D-38678 Clausthal-Zellerfeld, Germany |
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Abstract: | The polymer-solvent interaction was studied for two similar cellulose derivatives in the semi-dilute concentration range by static and dynamic light scattering. The trisubstituted 3-chlorophenyl carbamate (3Cl-CTC) and a mixed trisubstituted derivative with methyl groups (degree of methyl substituents: DS
Me = 1.6–1.7)combined with the abovementioned 3-chlorophenyl carbamate groups filling the still open positions at the cellulose backbone were synthesized, fractionated and characterized according to standard methods. Different kinds of associations, entangled clusters with a rod-like shape on one side and entanglement networks on the other side, exist in semi-dilute dioxane solutions caused by different polymer-solvent interactions. These quite different associations lead to either a liquid crystalline or a gel-like state upon increase of concentration. |
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Keywords: | semi-dilute solution cellulose urethane light scattering (static dynamic) aggregation phenomena |
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