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Olefin cross-metathesis based approach for the stereoselective total synthesis of (+)-cardiobutanolide
Authors:Palakodety Radha Krishna  E. Shiva Kumar
Affiliation:D-211, Discovery Laboratory, Organic Chemistry Division-III, Indian Institute of Chemical Technology, Hyderabad 500 607, India
Abstract:Olefin cross-metathesis approach to (+)-cardiobutanolide has been achieved starting from d-mannitol utilizing Sharpless kinetic resolution and Sharpless asymmetric dihydroxylation.
Keywords:Olefin cross-metathesis   Grubbs&rsquo   catalyst   Sharpless kinetic resolution   Sharpless asymmetric dihydroxylation     smallcaps"  >d-Mannitol
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