Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates |
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| Authors: | Yanying Zhang Koichi Mitsudo Shunzo Suematsu Daisuke Horii Kenji Tamamitsu |
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| Institution: | a Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Okayama 700-8530, Japan
b Research Center, Nippon Chemi-con Corporation, 363 Takahagi, Ibaraki 318-8505, Japan |
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| Abstract: | Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from −2.5 to 1.5 V vs Ag/Ag+), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials. |
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