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Studies of Tertiary Amine Oxides. Part1 15. Carbon - 13 nuclear magnetic resonance spectra of some N-(4-substituted phenyl) piperidine,the corresponding N-oxides,and their thermal-rearrangement product
Authors:Abdul-Hussain Khuthier  Jasim M A Al-rawi  Salim Y Hanna
Institution:Department of Chemistry , College of Science, University of Mosul , Mosul, IRAQ
Abstract:The carbon-13 chemical shifts of seven N-(4-substituted phenyl) piperidine; the corresponding N-oxides, and their thermal rearrangement products were analyzed and assigned. The N-oxidation effect on the carbon-13 chemical shift is discussed, a correlation of N-oxidation effect with substituent constant (σp, σm, σI and σR) has been studied; dual substituent-parameter equation produce better correlation.
Keywords:MRI dosimetry  Proton relaxation times  Fluorescence  Protein-polymer gel (PIRA)  Phantom material  Fricke-doped gels
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