Solvatochromism of Ternary Iron (II) Diimine Cyanide Complexes in 2-Ethyl-2-(hydroxymethyl) 1,3-Propanediol (Trimethylol Propane) |
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Authors: | Bassem F. Shraydeh John Burgess |
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Affiliation: | 1. Chemistry Department, Faculty of Science , An-Najah National University Nablus , West Bank, Via Israel;2. Department of Chemistry , University of Leicester , Leicester, LE1 7RH, U. K. |
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Abstract: | The solvatochromic behaviour of bis-(2,2′-bipyridyl)-biscyanoiron (II) and 2,2′- bipyridyltetracyanoiron (II) in 2-ethyl-2-(hydroxymethyl)-1,3-propanediol has been established. The significance and sensitivities of the solvatochromic shifts of these charge-transfer bands are outlined for the two iron complexes above. |
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Keywords: | Solvatochromism 2-ethyl-2-(hydroxymethyl) 1,3-propanediol 2,2′-bipyridyltetracyanoiron (II) bis-(2,2′- bipyridyl) biscyanoiron (II) |
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