Force Constants,Coriolis Coupling Constants,and Mean Amplitudes of Vibration of InCl6 3- |
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| Authors: | A. K. Dublish D. K. Sharma |
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| Affiliation: | 1. Department of Physics , Meerut University , Meerut;2. Department of Physics , Meerut College , Meerut |
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| Abstract: | Abstract The general quadratic force constants, coriolis coupling constants and mean amplitudes of vibration have been evaluated for InCl6 3- using recent vibrational data. The results are employed to study the trend of variation in the isoelectronic sequences e.g. InCl6 3-, SnCl6 2- and SbCl6 ?. In the present communication we report the force constants, coriolis coupling constants and mean amplitudes of vibration for InCl6 3- which have not been reported so far. The results are used to study the trend of variation of the molecular parameters in the isoelectronic sequence e.g. InCl6 3-, SnCl6 2- and SbCl6 ?. The fundamental frequencies of InCl6 3-, employed in this computation, have been reported on the basis of octahedral symmetry, from infrared and Raman Spectral Studies1. |
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