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Raman and IR Spectroscopy of a Mixed CH3CN-H2O Solvent in the Cn Stretching Region |
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| Authors: | Mitko Stoev Artiom Makarow Jóse Maria A Robledo |
| Institution: | 1. Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences , 1113, Sofia, Bulgaria;2. Department of Inorganic Chemistry, Chemical Faculty , Sankt-Petersburg State University , 198904, St. Petersburg, Russia;3. Universidad de Castilla-La Mancha, Escuela Universitaria de Ingenieria, Technica Agricola , 13004, Ciudad Real, Spain |
| Abstract: | Raman and IR spectroscopy have been used to elucidate the solvation process in a mixed water-acetonitrile solvent in the CN stretching region. The number and positions of the components forming the spectral contour are established by Fourier deconvolution and Factor analysis and their areas are determined by fitting. The forms of existence of acetonitrile in the mixed solvent are discussed. |
| Keywords: | Acetonitrile Solvation Raman IR Fourier Deconvolution Fit |