|
|||||
|
|
Highly Chemoselective Thiocarbonyl Oxidation upon Reaction of 4-Methyl-3-phenyl-2-thiazolidinethione with Singlet Oxygen |
|
| Authors: | Siddik İaçli Stephen T. Astley Celil Timur Altan Altmok |
| Affiliation: | 1. TUBITAK-Marmara Research Center, Research Institute for Basic Sciences, Department of Chemistry , P.O. Box 21, 41470, Gebze-Kocaeli, TURKEY;2. Department of Chemistry , Faculty of Science, Ege University , Bornova-?zmir, TURKEY;3. Turk Hoechst A.?. , Davutpa?a Cadd. 145, Topkapi-?stanbul, TURKEY |
| Abstract: | 4-Methyl-3-phenyl-2-thiazolidinethione was reacted with both photochemically and chemically generated singlet oxygen. Despite reaction conditions which were selected to favor oxidation of the sulfide group, both reactions afforded a single product arising solely from thiocarbonyl oxidation. |
| Keywords: | PA spectra, rare earth ternary complex |