Vibrational Parameters of Some Mixed Tetracoordinate Halogenomercurate(II) Complexes |
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| Authors: | A N Pandey A Bigotto S Mohan |
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| Institution: | 1. International Centre for Theoretical Physics , Trieste, Italy;2. Department of Chemical Sciences , University of Trieste , P. le Europa 1, 34127, Trieste, Italy;3. Department of Physics , Anna University , Madras, India |
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| Abstract: | Abstract The normal coordinate analysis has been performed for the mercury(II) halogeno complexes HgX3Y2? (X≠Y=C1, Br, I) using latest Raman spectral data for the first time. The general quadratic valence force field has been used in this study. The results in turn are utilized to investigate the useful vibrational parameters such as compliance constants and mean amplitudes of vibration. The trends among the vibrational parameters are discussed and the bond properties of the mercury(II) and related complexes are examined. |
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| Keywords: | force constants GQVFF dynamic parameters tetracoordinste halogenomercurates |
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