A 19F NMR Study on the Interaction of the Hexafluoroanions of Group IV Elements with Cations in Solutions |
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| Authors: | B N Chernyshov V A Shcherbakov R L Davidovich |
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| Institution: | Institute of Chemistry, Far East Science Center, USSR Academy of Sciences , Vladivostok, 22, USSR |
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| Abstract: | In view of previous studies of tetrafluoroborate solutions1, it appeared interesting to continue further investigations on the interactions of fluorocomplexes with different cations, in general, and of the MF6 2- fluoro complexes, in particular. In this communication, the high resolution 19F NMR data are given for the aqueous and water-acetone solutions of silicon, germanium, tin and titanium hexafluorocomplexes, containing paramagnetic (Co2+, Ni2+, Cu2+, Cr3+) and diamagnetic (Be2+, Mg2+, Zn2+, NH4 +) cations. |
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| Keywords: | NMR spectra hexafluorocomplexes |
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