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The Infrared Spectrum of Solid Chlorotrifluoromethane
Authors:D. O. Frazier  S. Bhatia  B. H. Loo
Affiliation:1. Space Science Laboratory , NASA Marshall Space Flight Center Huntsville , AL, 35812;2. Dolphus E. Milligan Science Research Institute Atlanta University Center Inc. , Atlanta, GA, 30310;3. Department of Chemistry , The University of Alabama in Huntsville Huntsville , AL, 35899
Abstract:The Infrared spectrum of solid chlorotrifluoromethane (CF3Cl) has been studied and compared with that of matrix-isolated CF3Cl. Crystal field splitting patterns of the strongest modes ν1 and ν4 suggest the crystal structure to be orthorhombic with a C2v factor group and two molecules per unit cell located on Cs sites.
Keywords:Infrared spectroscopy  chlorotrifluoromethane
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