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Application of the Keating Bendings to ALCL3 and SO3: Preliminary Communication
Authors:S J Cyvin  B N Cyvin  T Mogstad  J Brunvoll  G Díaz Fleming
Institution:1. Division of Physical Chemistry , The University of Trondheim , N-7034, Trondheim-NTH, Norway;2. Departmento de Quimica , Universidad Catolica de Valparaiso , Casilla, 4059, Valparaiso, Chile
Abstract:Force fields from literature for the degenerate (E') vibrations of AlCl3 and SO3 are transferred from the valence symmetry coordinates to the central- and Keating symmetry coordinates. In both cases it is found |F 12 k| > |F 12| > |F 12 c|.
Keywords:Force contants  Keating's bending  Aluminum trichloride monomer  Sulfur trioxide monomer
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