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Complete Analysis of the 1H and 13C NMR Spectra of 5-Isopropylsulfonyl-2-Norbornenes Through the Application of Two-Dimensional NMR Techniques |
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| Authors: | J-M Mattalia A Samat R Faure M Chanon |
| Institution: | URA CNRS 1411, Université d'Aix-Marseille III, Faculté des Sciences de Saint-Jérome , Avenue Escadrille Normandie -Niemen, 13397, Marseille Cedex, 13, France |
| Abstract: | Total assignment of 13C and 1H NMR spectra of the 5-isopropylsulfonyl-2-norbornenes 2 was achieved using the concerted application of two-dimensional homonuclear and heteronuclear chemical shift correlations. The stereochemistry of both the diastereoisomers endo 2a and exo 2b have been established using the magnitude of the proton coupling constants. |
| Keywords: | 5-isopropylsulfonyl-2-norbornenes 1H-1H homonuclear and 1H-13C heteronuclear two-dimensional chemical shift correlations 1H NMR 13C NMR |