Enhanced Fluorimetric Determination of Samarium with Dibenzoylmethane and Diphenylguanidine by Gadolinium |
| |
Authors: | I. Hornyák J. Erostyák A. Buzády A. Kaszás L. Kozma |
| |
Affiliation: | Janus Pannonius University, Department of Experimental Physics , H-7624 Pécs, Ifjúság u. 6., Hungary |
| |
Abstract: | Abstract The fluorescence of Sm-dibenzoylmethane (DBM)-diphenylguanidine (DPG) system was enhanced by about two to three orders of magnitude when it was excited in the presence of Gd in ethanol-water solution. The excitation and emission wavelegths were 390 nm and 652 nm, respectively. The fluorescence intensity was a linear function of the concentration of Sm in the range of 1.0 × 10?9–2.0 × 10?6 M. The fluorescence mechanism of the system is discussed. |
| |
Keywords: | Samarium Complex Sensitized Luminescence Energy Transfer |
|