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Enhanced Fluorimetric Determination of Samarium with Dibenzoylmethane and Diphenylguanidine by Gadolinium
Authors:I. Hornyák  J. Erostyák  A. Buzády  A. Kaszás  L. Kozma
Affiliation:Janus Pannonius University, Department of Experimental Physics , H-7624 Pécs, Ifjúság u. 6., Hungary
Abstract:Abstract

The fluorescence of Sm-dibenzoylmethane (DBM)-diphenylguanidine (DPG) system was enhanced by about two to three orders of magnitude when it was excited in the presence of Gd in ethanol-water solution. The excitation and emission wavelegths were 390 nm and 652 nm, respectively. The fluorescence intensity was a linear function of the concentration of Sm in the range of 1.0 × 10?9–2.0 × 10?6 M. The fluorescence mechanism of the system is discussed.
Keywords:Samarium Complex  Sensitized Luminescence  Energy Transfer
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