1H NMR Spectral Simplification with Achiral and Chiral Lanthanide Shift Reagents. Methastyridone, 2,2-Dimethyl-5-(2-Phenylethenyl)-4-Oxazolidinone |
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Authors: | Joel Ross Robert Rothchild |
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Institution: | 1. Physics Department , St. Michael's College , Winooski Park, Colchester, VT, 05439;2. The City University of New York, John Jay College of Criminal Justice, Toxicology Research and Training Center, Department of Science , 445 West 59th Street, New York, NY, 10019-1199 |
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Abstract: | Abstract The 60 MHz 1H NMR spectra of methastyridone, 2,2-dimethyl-5-(2-phenylethenyl)-4-oxazolidinone, 1, have been studied at 28° in CDCl3 solution with the achiral reagent tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III), 2, Eu(FOD)3, and the chiral reagent tris3-(heptafluoropropylhydroxy-methylene)-d?camphorato]europium(III), 3, Eu(HFC)3. |
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Keywords: | Europium Praseodymium Optical Purity Enantiomer Pr(FOD)3 Pr(HFC)3 Eu(FOD)3 Eu(HFC)3 Analysis |
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