The Synthesis,Vibrational Spectra,Electronic Spectra,and Thermal Analysis of Some Mixed Complexes with Planar Dithiooxamides |
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Authors: | M. Bellaihou H. O. Desseyn |
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Affiliation: | Laboratorium voor Anorganische Scheikunde , R.U.C.A. Universiteit Antwerpen , Groenenborgerlaan 171, 2020, Antwerpen, Belgium |
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Abstract: | Planar Pd(LH)2 complexes (LH2 = H2N C S C S N H2, CH3HNCSCSNHCH3) form mixed polymeric complexes with Ni(II), Cu(II), Zn(II) and Cd(II) in alcalic media, where the planar Pd(LH)2 complexes act as tetradentates with N-coordination. The electronic spectra and thermal behaviour are discussed, a thorough investigation of the i.r. spectra is presented and special attention has been given to the H/D, CH3/CD3 and 58Ni/62Ni, 63Cu/65Cu and 64Zn/68Zn isotopic shifts. |
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Keywords: | Vibrational spectra complexes dithiooxamides |
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