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Electric field gradients in Hf2Fe
Authors:SM Van Eek  AF Pasquevich
Institution:(1) Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67, 1900 La Plata, Argentina
Abstract:Perturbed Angular Correlations (PAC) technique was applied to measure the electric field gradients (EFG) at 181Ta sites in Hf2Fe. The compound has the cubic structure of the Ti2Ni prototype with two non‐equivalent crystallographic sites for Hf atoms. EFGs for the two sites were measured as a function of the temperature. In addition, one more EFG was observed, which was assigned to the presence of defects in the lattice. The ratio of the measured EFG at the regular lattice sites has been used to assign charges to the ions through a simple calculation using the point charge model and it is shown that the lattice symmetry can explain the very different EFG at both sites. This revised version was published online in August 2006 with corrections to the Cover Date.
Keywords:electric field gradients  Hf2Fe  point charges model
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