| 衍生气相色谱-质谱法测定水中氯代酸性除草剂 |
| |
| 引用本文： | 张莉,张永涛,桂建业,左海英,李桂香.衍生气相色谱-质谱法测定水中氯代酸性除草剂[J].分析试验室,2010,29(3). |
| |
| 作者姓名： | 张莉 张永涛 桂建业 左海英 李桂香 |
| |
| 作者单位： | 1. 中国地质科学院水文地质环境地质研究所,正定,050803
2. 澳实分析检测(上海)有限公司,上海,201206 |
| |
| 基金项目： | 国家自然科学基金(40672169);;中国地质科学院水文地质环境地质研究所基本科研业务费(SK07001)项目资助 |
| |
| 摘 要： | 采用H2SO4加入法改变了酸性除草剂在水中的存在状态,对碱性活化点的存在与消除进行了分析,同时对不同试剂的萃取效率进行了对比,建立了衍生气相色谱-质谱法测定水中10种氯代酸性除草剂的方法。化合物检出限均低于10.0 ng/L,回收率范围为60%～120%。
|
| 关 键 词： | 碱性活化点 衍生 氯代酸性除草剂 气相色谱-质谱 |
Derivative gas chromatography-mass spectrometric determination of chloro-substituted acid herbicide in water samples with elimination of activited points of alkaline |
| |
| ZHANG Li,ZHANG Yong-tao,GUI Jian-ye,ZUO Hai-ying,LI Gui-xiang.Derivative gas chromatography-mass spectrometric determination of chloro-substituted acid herbicide in water samples with elimination of activited points of alkaline[J].Chinese Journal of Analysis Laboratory,2010,29(3). |
| |
| Authors: | ZHANG Li ZHANG Yong-tao GUI Jian-ye ZUO Hai-ying LI Gui-xiang |
| |
| Abstract: | By changing existing form of acid herbicide with adding sulfuric acid,existing and eliminating of activated points on alkaline were analyzed,and comparison of different reagents,a derivative gas chromatography-mass spectrometry which can detect 10 kinds of acid herbicides in water is developed.Its detection limit can be below 10.0 ng/L and recoveries are between 60% and 120%. |
| |
| Keywords: | Activited points of alkaline Derivative Chloro-substituted acid herbicide Gas chromatography-mass spectrometry |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
