Hydroxylation of phenol with hydrogen peroxide in protic and aprotic solvents on TS-1 catalyst |
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| Authors: | V V Potekhin V A Kulikova V V Vasil’ev E G Kohina V M Potekhin |
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| Institution: | (1) Department of Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu 501-1193, Japan |
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| Abstract: | Hydroxylation of phenol with a 25% aqueous solution of hydrogen peroxide in polar protic and aprotic solvents on TS-1 heterogeneous
catalyst under various conditions was studied. The major reaction products (hydroquinone, pyrocatechol) and their ratio were
determined. A kinetic model describing the hydroxylation in accordance with the Rideal-Eley mechanism was chosen. |
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