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Multipore Zeolites: Synthesis and Catalytic Applications
Authors:Dr Manuel Moliner  Dr Cristina Martínez  Prof Avelino Corma
Institution:1. Instituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas (UPV‐CSIC), Valencia, 46022 (Spain);2. King Fahd University of Petroleum and Minerals, P.O. Box 989, Dhahran 31261, Saudi Arabia
Abstract:In the last few years, important efforts have been made to synthesize so‐called “multipore” zeolites, which contain channels of different dimensions within the same crystalline structure. This is a very attractive subject, since the presence of pores of different sizes would favor the preferential diffusion of reactants and products through those different channel systems, allowing unique catalytic activities for specific chemical processes. In this Review we describe the most attractive achievements in the rational synthesis of multipore zeolites, containing small to extra‐large pores, and the improvements reported for relevant chemical processes when these multipore zeolites have been used as catalysts.
Keywords:heterogeneous catalysis  hydrothermal synthesis  molecular sieves  molecular traffic control  multipore zeolites
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